Patchy particles
The general model for a patchy particle [1] is given by [2]
- Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle u_{\mathrm {patchy} }({\mathbf {r} }_{ij},{\mathbf {\Omega } }_{i},{\mathbf {\Omega } }_{j})=\left\{{\begin{array}{lll}u_{\mathrm {LJ} }(r_{ij})&;&r_{ij}<\sigma _{\mathrm {LJ} }\\u_{\mathrm {LJ} }(r_{ij})\exp \left(-{\frac {\theta _{k_{min},ij}^{2}}{2\sigma ^{2}}}\right)\exp \left(-{\frac {\theta _{l_{min},ji}^{2}}{2\sigma ^{2}}}\right)&;&r_{ij}\geq \sigma _{\mathrm {LJ} }\end{array}}\right.}
where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle u_{\mathrm {LJ}}(r_{ij})} is the Lennard-Jones potential and

Anisotropy dimensions
Anisotropy dimensions is a classification scheme for patchy particles (See Figure 2 of [3]). The eight attributes are as follows:
Surface coverage (A)
Aspect ratio (B)
Faceting (C)
Pattern quantisation (D)
Branching (E)
Chemical ordering (F)
Shape gradient (G)
Roughness (H)
See also
- Colloids
- Emulsions
- Janus particles
- Kern and Frenkel patchy model
- Phase diagram of anisotropic particles with octahedral symmetry
- Phase diagram of anisotropic particles with tetrahedral symmetry
- Smith and Nezbeda associated fluid model
- Wertheim's first order thermodynamic perturbation theory (TPT1)
References
- ↑ Zhenli Zhang and Sharon C. Glotzer "Self-Assembly of Patchy Particles", Nano Letters 4 pp. 1407-1413 (2004)
- ↑ Jonathan P. K. Doye, Ard A. Louis, I-Chun Lin, Lucy R. Allen, Eva G. Noya, Alex W. Wilber, Hoong Chwan Kok and Rosie Lyus "Controlling crystallization and its absence: proteins, colloids and patchy models", Physical Chemistry Chemical Physics 9 pp. 2197-2205 (2007)
- ↑ Sharon C. Glotzer and Michael J. Solomon "Anisotropy of building blocks and their assembly into complex structures", Nature Materials 6 pp. 557-562 (2007)
Related reading