Virial pressure

This is a common method to obtain the pressure from a general simulation (it is best suited for molecular dynamics since forces are evaluated in this case). For central interactions, one has:

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle p={\frac {k_{B}TN}{V}}+{\frac {1}{dV}}{\overline {\sum _{i<j}{\mathbf {f} }_{ij}{\mathbf {r} }_{ij}}},}

where one can recognize an ideal term and another one due to the virial. The underline is an average, which would be a time average in molecular dynamics, or ensamble average in Monte Carlo; Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle d} is the dimension of the system (3 in actual world). Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle {\mathbf f}_{ij} } is the force on particle Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle i} exerted by particle Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle j} , and ${\mathbf {r} }_{ij}$ is the vector going from Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle i} to Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle j} : Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle {\mathbf r}_{ij} = {\mathbf r}_j - {\mathbf r}_i} .